胡宏成， 曾 韜*， 陳華成（南京林業(yè)大學(xué)化學(xué)工程學(xué)院，江蘇南京210037）

    摘 要：采用對(duì)甲苯磺酸催化蒎烯合成異松油烯，在反應(yīng)溫度90℃，反應(yīng)時(shí)間7 h，催化劑用量為原料質(zhì)量的12.7 %，水用量為原料質(zhì)量的36 %，乳化劑用量為原料質(zhì)量的1.3 %，異松油烯的含量和得率分別達(dá)到38.8 %和39.9 %。其合成工藝和產(chǎn)品得率都優(yōu)于和高于目前國內(nèi)外現(xiàn)有同類研究水平。

    關(guān)鍵詞：蒎烯；對(duì)甲苯磺酸；異松油烯

    中圖分類號(hào)：TQ351       文獻(xiàn)標(biāo)識(shí)碼：A       文章編號(hào)：1673-5854（2007）01-0019-03

Study on Synthesis of Terpinolene from Pinene
HU Hong-cheng,ZENG Tao,CHEN Hua-cheng
(College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China )

Abstract: Terpinolene was synthesized from pinene by the catalysis of p-tolueresulfonic acid.The final content of terpinolene in product could be maintained 38.8 % and the yield of terpinolene was 39.9 %. Under the condition of 90 ℃，7 h,12.7 % catalyst, 36 % water,1.3 % emulsifier.The synthesis technigue and yield of product are all superior than those at home and abroad.

Key words:  pinene;toluene-p-sulfonic acid;terpinolene